By a pseudopotential method, the perturbation of the outer electronic s and p levels of Cu, Ag, and Au atoms by a Ne matrix is calculated. It is concluded that for Cu and Au the trapping site consists of three vacancies. Two sites of three and four vacancies give the two different "triplets" in the absorption spectrum of Ag.
Isolated noble-metal atoms in a Neon matrix / Ossicini, Stefano; Forstmann, F.. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 21:(1982), pp. 1755-1757.
Isolated noble-metal atoms in a Neon matrix
OSSICINI, Stefano;
1982
Abstract
By a pseudopotential method, the perturbation of the outer electronic s and p levels of Cu, Ag, and Au atoms by a Ne matrix is calculated. It is concluded that for Cu and Au the trapping site consists of three vacancies. Two sites of three and four vacancies give the two different "triplets" in the absorption spectrum of Ag.
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