By a pseudopotential method the perturbation of the outer electronic s and p levels of Na and K by rare gas matrices is calculated. It is concluded that the stable trapping site consists of four vacancies, except for a substitutional site for Na in Xe. A metastable site of three vacancies gives the ''red triplet'' in the absorption spectrum.

Matrix effects on the optical spectra of alkali atoms trapped in Ar, Kr and Xe matrices: a pseudopotential calculations / Ossicini, Stefano; Forstmann, F.. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - STAMPA. - 75:(1981), pp. 2076-2079.

Matrix effects on the optical spectra of alkali atoms trapped in Ar, Kr and Xe matrices: a pseudopotential calculations

OSSICINI, Stefano;
1981

Abstract

By a pseudopotential method the perturbation of the outer electronic s and p levels of Na and K by rare gas matrices is calculated. It is concluded that the stable trapping site consists of four vacancies, except for a substitutional site for Na in Xe. A metastable site of three vacancies gives the ''red triplet'' in the absorption spectrum.
75
2076
2079
Matrix effects on the optical spectra of alkali atoms trapped in Ar, Kr and Xe matrices: a pseudopotential calculations / Ossicini, Stefano; Forstmann, F.. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - STAMPA. - 75:(1981), pp. 2076-2079.
Ossicini, Stefano; Forstmann, F.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/459105
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