A pseudopotential model is suggested for the calculation of the matrix perturbation on the spectra of isolated atoms. The calculated shifts of the ground state and of the excited state have different signs. The energy of the outer electron of the isolated atom is lowered in the substitutional site. A blue shift for the PS absorption lines of the right magnitude is calculated for Cu, Ag, and Au atoms on substitutional sites in Ar, Kr, and Xe matrices.

The influence of rare gas matrix on the electronic levels of isolated atoms / Forstmann, F.; Ossicini, Stefano. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - STAMPA. - 73:(1980), pp. 5997-6002.

The influence of rare gas matrix on the electronic levels of isolated atoms

OSSICINI, Stefano
1980

Abstract

A pseudopotential model is suggested for the calculation of the matrix perturbation on the spectra of isolated atoms. The calculated shifts of the ground state and of the excited state have different signs. The energy of the outer electron of the isolated atom is lowered in the substitutional site. A blue shift for the PS absorption lines of the right magnitude is calculated for Cu, Ag, and Au atoms on substitutional sites in Ar, Kr, and Xe matrices.
73
5997
6002
The influence of rare gas matrix on the electronic levels of isolated atoms / Forstmann, F.; Ossicini, Stefano. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - STAMPA. - 73:(1980), pp. 5997-6002.
Forstmann, F.; Ossicini, Stefano
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/459104
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 36
  • ???jsp.display-item.citation.isi??? 47
social impact