The Me3SiCl-Me2SO system is an efficient reagent for the smooth chlorination of unconjugated carbonyl compds. at the more substituted α-carbon atom. β-Dicarbonyl substrates are transformed into α-chloro-α-thiomethyl ether derivs.
REACTIONS OF THE TRIMETHYLCHLOROSILANE-DIMETHYL SULPHOXIDE REAGENT WITH CARBONYL COMPOUNDS / Bellesia, Franco; Ghelfi, Franco; Grandi, Romano; Pagnoni, Ugo Maria. - In: JOURNAL OF CHEMICAL RESEARCH. SYNOPSES. - ISSN 0308-2342. - STAMPA. - /:(1986), pp. 426-427.
REACTIONS OF THE TRIMETHYLCHLOROSILANE-DIMETHYL SULPHOXIDE REAGENT WITH CARBONYL COMPOUNDS
BELLESIA, Franco;GHELFI, Franco;GRANDI, Romano;PAGNONI, Ugo Maria
1986
Abstract
The Me3SiCl-Me2SO system is an efficient reagent for the smooth chlorination of unconjugated carbonyl compds. at the more substituted α-carbon atom. β-Dicarbonyl substrates are transformed into α-chloro-α-thiomethyl ether derivs.
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