Pyrroles are powerful nucleophiles in the reaction with dialkyl sulfoxides and trimethylchlorosilane (TMCS) or trimethylbromosilane (TMBS), affording sulfonium salts or halo derivatives, generally in good yields.
THE REACTION OF PYRROLES WITH TRIMETHYLHALOSILANES-DIALKYL SULFOXIDES / Bellesia, Franco; Ghelfi, Franco; Grandi, Romano; Pagnoni, Ugo Maria; Pinetti, Adriano. - In: JOURNAL OF HETEROCYCLIC CHEMISTRY. - ISSN 0022-152X. - STAMPA. - 30:(1993), pp. 617-621.
THE REACTION OF PYRROLES WITH TRIMETHYLHALOSILANES-DIALKYL SULFOXIDES
BELLESIA, Franco;GHELFI, Franco;GRANDI, Romano;PAGNONI, Ugo Maria;PINETTI, Adriano
1993
Abstract
Pyrroles are powerful nucleophiles in the reaction with dialkyl sulfoxides and trimethylchlorosilane (TMCS) or trimethylbromosilane (TMBS), affording sulfonium salts or halo derivatives, generally in good yields.
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