Treatment of oximes and semicarbazones of saturated and (alpha,beta-unsaturated ketones and aldehydes with trimethylchlorosilane-dimethyl sulphoxide in dry acetonitrile affords the corresponding carbonyl compounds in excellent yields under mild conditions.
CARBONYL REGENERATION FROM OXIMES AND SEMICARBAZONES BY TRIMETHYLCHLOROSILANE-DIMETHYLSULFOXIDE / Ghelfi, Franco; Grandi, Romano; Pagnoni, Ugo Maria. - In: SYNTHETIC COMMUNICATIONS. - ISSN 0039-7911. - STAMPA. - 23:(1993), pp. 2279-2284.
CARBONYL REGENERATION FROM OXIMES AND SEMICARBAZONES BY TRIMETHYLCHLOROSILANE-DIMETHYLSULFOXIDE
GHELFI, Franco;GRANDI, Romano;PAGNONI, Ugo Maria
1993
Abstract
Treatment of oximes and semicarbazones of saturated and (alpha,beta-unsaturated ketones and aldehydes with trimethylchlorosilane-dimethyl sulphoxide in dry acetonitrile affords the corresponding carbonyl compounds in excellent yields under mild conditions.
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