[Fe10O4(OMe)16(dbm)6]·xCHCl3 (1) was prepd. and characterized by x-ray crystallog. The crystal lattice contains decairon clusters and highly disordered chloroform mols. The temp. dependence of the magnetic susceptibility of 1 was investigated and the magnetic behavior was indicative of strong antiferromagnetic interactions.
Structure and Magnetic Properties of a Decanuclear Oxoiron(III) Cluster: A Further Step to Understanding Iron Aggregation Processes / A., Caneschi; Cornia, Andrea; FABRETTI COSTANTINO, Antonio; D., Gatteschi. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH. - ISSN 0570-0833. - STAMPA. - 34:(1995), pp. 2716-2718.
Structure and Magnetic Properties of a Decanuclear Oxoiron(III) Cluster: A Further Step to Understanding Iron Aggregation Processes
CORNIA, Andrea;FABRETTI COSTANTINO, Antonio;
1995
Abstract
[Fe10O4(OMe)16(dbm)6]·xCHCl3 (1) was prepd. and characterized by x-ray crystallog. The crystal lattice contains decairon clusters and highly disordered chloroform mols. The temp. dependence of the magnetic susceptibility of 1 was investigated and the magnetic behavior was indicative of strong antiferromagnetic interactions.
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