Esters and amides (including N-15 analogs) of 1-alkoxyaziridine-2,2-dicarboxylic acids that contain N-alkoxy substituents ((PrO)-O-i, RO2CCH2O, (R,S)-RO2CCH(Me)O, or (S)-RO2CCH(Me)O) were synthesized. Triamide of the last-mentioned type was isolated in the diastereomerically pure forms. The validity of the H-1 NMR criteria, which were suggested for the determination of absolute configurations of diastereomers, was confirmed by X-ray diffraction study of the (S,S)-form.

Asymmetric nitrogen - 80. Diastereomeric derivatives of 1-alkoxyaziridine-2,2-dicarboxylic acids. Synthesis, structure, and absolute configuration / Prosyanik, Av; Rozhkov, Vv; Moskalenko, As; Mishchenko, Ai; Forni, Arrigo; Moretti, Irene; Torre, Giovanni; Brukner, S; Malpezzi, L; Kostyanovsky, Rg. - In: RUSSIAN CHEMICAL BULLETIN. - ISSN 1066-5285. - STAMPA. - 47:(1998), pp. 119-126.

Asymmetric nitrogen - 80. Diastereomeric derivatives of 1-alkoxyaziridine-2,2-dicarboxylic acids. Synthesis, structure, and absolute configuration

FORNI, Arrigo;MORETTI, Irene;TORRE, Giovanni;
1998

Abstract

Esters and amides (including N-15 analogs) of 1-alkoxyaziridine-2,2-dicarboxylic acids that contain N-alkoxy substituents ((PrO)-O-i, RO2CCH2O, (R,S)-RO2CCH(Me)O, or (S)-RO2CCH(Me)O) were synthesized. Triamide of the last-mentioned type was isolated in the diastereomerically pure forms. The validity of the H-1 NMR criteria, which were suggested for the determination of absolute configurations of diastereomers, was confirmed by X-ray diffraction study of the (S,S)-form.
1998
47
119
126
Asymmetric nitrogen - 80. Diastereomeric derivatives of 1-alkoxyaziridine-2,2-dicarboxylic acids. Synthesis, structure, and absolute configuration / Prosyanik, Av; Rozhkov, Vv; Moskalenko, As; Mishchenko, Ai; Forni, Arrigo; Moretti, Irene; Torre, Giovanni; Brukner, S; Malpezzi, L; Kostyanovsky, Rg. - In: RUSSIAN CHEMICAL BULLETIN. - ISSN 1066-5285. - STAMPA. - 47:(1998), pp. 119-126.
Prosyanik, Av; Rozhkov, Vv; Moskalenko, As; Mishchenko, Ai; Forni, Arrigo; Moretti, Irene; Torre, Giovanni; Brukner, S; Malpezzi, L; Kostyanovsky, Rg...espandi
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/8539
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 3
  • ???jsp.display-item.citation.isi??? 4
social impact