Transparent light-emitting hybrid materials are produced by UV curing of acrylic resins containing silica precursors and photoluminescent [Cu4I4L4] clusters. Acrylic double-bond conversion is followed by means of FT-IR spectroscopy, and optical measurements are performed on cured films showing a high transparency of the films up to a content of 30wt% TEOS and a bright luminescence with a maximum of emission centered at 565nm (yellow-orange). This study shows the possibility to obtain new advanced materials in which functional properties such as photoluminescence and scratch resistance are successfully conjugated in a hybrid film that maintains high transparency.
Multifunctional Luminescent Organic/ Inorganic Hybrid Films / Ignazio, Roppolo; Messori, Massimo; Sandrine, Perruchas; Thierry, Gacoin; Jean Pierre, Boilot; Marco, Sangermano. - In: MACROMOLECULAR MATERIALS AND ENGINEERING. - ISSN 1438-7492. - STAMPA. - 297:7(2012), pp. 680-688. [10.1002/mame.201100267]
Multifunctional Luminescent Organic/ Inorganic Hybrid Films
MESSORI, Massimo;
2012
Abstract
Transparent light-emitting hybrid materials are produced by UV curing of acrylic resins containing silica precursors and photoluminescent [Cu4I4L4] clusters. Acrylic double-bond conversion is followed by means of FT-IR spectroscopy, and optical measurements are performed on cured films showing a high transparency of the films up to a content of 30wt% TEOS and a bright luminescence with a maximum of emission centered at 565nm (yellow-orange). This study shows the possibility to obtain new advanced materials in which functional properties such as photoluminescence and scratch resistance are successfully conjugated in a hybrid film that maintains high transparency.
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