The stoichiometry of the reduction reaction and D-galacturonic acid with iron(III) has been determined, leading to a 4:1 ratio between the quantities of reduced iron and oxidized D-galacturonic acid, respectively. This last molecule is oxidized to formic acid, and the residue is thought to present a further terminal carboxylic group. The reducing predominant species appears to be the FeGal3 complex.
Complexing and redox properties of the system D-galacturonic acid-iron(III) / S., Deiana; C., Gessa; V., Solinas; P., Piu; Seeber, Renato. - In: JOURNAL OF INORGANIC BIOCHEMISTRY. - ISSN 0162-0134. - STAMPA. - 35:(1989), pp. 107-113. [10.1016/0162-0134(89)80003-0]
Complexing and redox properties of the system D-galacturonic acid-iron(III)
SEEBER, Renato
1989
Abstract
The stoichiometry of the reduction reaction and D-galacturonic acid with iron(III) has been determined, leading to a 4:1 ratio between the quantities of reduced iron and oxidized D-galacturonic acid, respectively. This last molecule is oxidized to formic acid, and the residue is thought to present a further terminal carboxylic group. The reducing predominant species appears to be the FeGal3 complex.
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