The electrochemical behaviour of Cp3UBH4 and Cp3UNEt2 in THF has been studied using cyclic voltammetry and chronoamperometry. Cp3UBH4 undergoes a simple one-electron quasi-reversible reduction, while chemical reactions between the product of the charge-transfer reaction and the starting electroactive species occur both after oxidation and reduction of Cp3UNEt2.
Electrochemical study of triscyclopentadienyluranium complexes / F., Ossola; P., Zanella; P., Ugo; Seeber, Renato. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 147:(1988), pp. 123-126. [10.1016/S0020-1693(00)80640-4]
Electrochemical study of triscyclopentadienyluranium complexes
SEEBER, Renato
1988
Abstract
The electrochemical behaviour of Cp3UBH4 and Cp3UNEt2 in THF has been studied using cyclic voltammetry and chronoamperometry. Cp3UBH4 undergoes a simple one-electron quasi-reversible reduction, while chemical reactions between the product of the charge-transfer reaction and the starting electroactive species occur both after oxidation and reduction of Cp3UNEt2.Pubblicazioni consigliate
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