The electrochemical behaviour of the complex [Co{P(OEt)3}2(NO)2][BPh4] has been studied in acetonitrile, using platinum and mercury electrodes. It undergoes two subsequent reduction processes and a single oxidation process. In particular, the less cathodic one-electron reduction leads to the formation of the corresponding neutral species which is fairly stable in carefully deaerated solution.
Electrochemical behaviour of dinitrosylbis(triethyl phosphite)-cobalt(I) tetraphenylborate in acetonitrile / Seeber, Renato; Gabriele, Albertin; Gian Antonio, Mazzocchin. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - STAMPA. - 1982:(1982), pp. 2561-2562. [10.1039/dt9820002561]
Electrochemical behaviour of dinitrosylbis(triethyl phosphite)-cobalt(I) tetraphenylborate in acetonitrile
SEEBER, Renato;
1982
Abstract
The electrochemical behaviour of the complex [Co{P(OEt)3}2(NO)2][BPh4] has been studied in acetonitrile, using platinum and mercury electrodes. It undergoes two subsequent reduction processes and a single oxidation process. In particular, the less cathodic one-electron reduction leads to the formation of the corresponding neutral species which is fairly stable in carefully deaerated solution.
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