Cyclic voltammetry, chronoamperometry and controlled potential coulometry are employed to study the cathodic and anodic behavior of the complex between Ni(II) and the extended rr system N,N'-ethylenebis(monothioacetylacetonimine) in cetonitrile solvent at platinum and mercury electrodes The reduction process leads to the corresponding Ni(I) complex, stable in the electrolysis solution;the oxidation product proves to be a fourcharged cationic complex with structural features very similar to those of the starting compound.The initial complex species can be electrolytically regenerated both from the oxidized and reduced species in a quantitative yield
Voltammetric behaviour of transition metal complexes with extended π systems schiff base ligands The N,N′-ethylenebis(monothyoacetylaceton-iminato)nickel(II) complex / A., Cinquantini; R., Cini; Seeber, Renato; P., Zanello. - In: JOURNAL OF ELECTROANALYTICAL CHEMISTRY AND INTERFACIAL ELECTROCHEMISTRY. - ISSN 0022-0728. - STAMPA. - 111:(1980), pp. 309-318. [10.1016/0368-1874(80)80264-4]
Voltammetric behaviour of transition metal complexes with extended π systems schiff base ligands The N,N′-ethylenebis(monothyoacetylaceton-iminato)nickel(II) complex
SEEBER, Renato;
1980-01-01
Abstract
Cyclic voltammetry, chronoamperometry and controlled potential coulometry are employed to study the cathodic and anodic behavior of the complex between Ni(II) and the extended rr system N,N'-ethylenebis(monothioacetylacetonimine) in cetonitrile solvent at platinum and mercury electrodes The reduction process leads to the corresponding Ni(I) complex, stable in the electrolysis solution;the oxidation product proves to be a fourcharged cationic complex with structural features very similar to those of the starting compound.The initial complex species can be electrolytically regenerated both from the oxidized and reduced species in a quantitative yield
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