EnglishCyclic voltammetry, chronoamperometry and controlled potential coulometry are employed to study the cathodic and anodic behavior of the complex between Ni(II) and the extended rr system N,N'-ethylenebis(monothioacetylacetonimine) in cetonitrile solvent at platinum and mercury electrodes The reduction process leads to the corresponding Ni(I) complex, stable in the electrolysis solution;the oxidation product proves to be a fourcharged cationic complex with structural features very similar to those of the starting compound.The initial complex species can be electrolytically regenerated both from the oxidized and reduced species in a quantitative yield
Voltammetric behaviour of transition metal complexes with extended π systems schiff base ligands The N,N′-ethylenebis(monothyoacetylaceton-iminato)nickel(II) complex / A., Cinquantini; R., Cini; Seeber, Renato; P., Zanello. - In: JOURNAL OF ELECTROANALYTICAL CHEMISTRY AND INTERFACIAL ELECTROCHEMISTRY. - ISSN 0022-0728. - STAMPA. - 111(1980), pp. 309-318.
| Data di pubblicazione: | 1980 |
| Titolo: | Voltammetric behaviour of transition metal complexes with extended π systems schiff base ligands The N,N′-ethylenebis(monothyoacetylaceton-iminato)nickel(II) complex |
| Autore/i: | A., Cinquantini; R., Cini; Seeber, Renato; P., Zanello |
| Autore/i UNIMORE: | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/0368-1874(80)80264-4 |
| Rivista: | |
| Volume: | 111 |
| Pagina iniziale: | 309 |
| Pagina finale: | 318 |
| Codice identificativo Scopus: | 2-s2.0-33748480536 |
| Citazione: | Voltammetric behaviour of transition metal complexes with extended π systems schiff base ligands The N,N′-ethylenebis(monothyoacetylaceton-iminato)nickel(II) complex / A., Cinquantini; R., Cini; Seeber, Renato; P., Zanello. - In: JOURNAL OF ELECTROANALYTICAL CHEMISTRY AND INTERFACIAL ELECTROCHEMISTRY. - ISSN 0022-0728. - STAMPA. - 111(1980), pp. 309-318. |
| Tipologia | Articolo su rivista |
File in questo prodotto:
I documenti presenti in Iris Unimore sono rilasciati con licenza Creative Commons Attribuzione - Non commerciale - Non opere derivate 3.0 Italia, salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
Copyright © 2021