The anodic behaviour of TcCl(CO)2(PMe2Ph)3 and TcCl(CO)3(PMe2Ph)2 complexes has been studied in acetonitrile solvent. Both the complex undergo an overall two-electron oxidation process with the formation of Tc(III) species; the electrode mechanism leading to their formation has been studied. In particular the [TcCl(CO)(MeCN)2(PMe2Ph)3][ClO4]2 compound has been isolated and characterized.
Voltammetric behaviour of technetium99 complexes with π-acceptor ligands in aprotic medium. III. Oxidation of technetium(I) complexes with phosphine and carbon monoxide ligands / U., Mazzi; E., Roncari; Seeber, Renato; G. A., Mazzocchin. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 41:(1980), pp. 95-98. [10.1016/S0020-1693(00)88436-4]