The voltammetric behaviour of cis-[Pt(PEt3)2(YC6H4)2] complexes in acetonitrile has been investigated by cyclic voltammetry and controlled potential coulometry. The oxidation potential increases linearly with increasing electron-withdrawing ability of the Y substituent in the platinum-bonded aryl ligand. The data are related to studies of electrophilic Pt—C bond cleavage.
Voltammetric behaviour of cis-diarylbis(triethylphosphine)platinum(II) complexes / Seeber, Renato; G. A., Mazzocchin; D., Minniti; R., Romeo; P., Uguagliati; U., Belluco. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - STAMPA. - 157:(1978), pp. 69-74. [10.1016/S0022-328X(00)83296-9]
Voltammetric behaviour of cis-diarylbis(triethylphosphine)platinum(II) complexes
SEEBER, Renato;
1978
Abstract
The voltammetric behaviour of cis-[Pt(PEt3)2(YC6H4)2] complexes in acetonitrile has been investigated by cyclic voltammetry and controlled potential coulometry. The oxidation potential increases linearly with increasing electron-withdrawing ability of the Y substituent in the platinum-bonded aryl ligand. The data are related to studies of electrophilic Pt—C bond cleavage.Pubblicazioni consigliate
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