The isomerization offac-[ReCl(CO)3(PMe2Ph)2]+ to the corresponding meridional-trans isomer has been studied by electroanalytical techniques in MeCN solvent. Chronoamperometric and cyclic voltammetric data relative to the oxidation offac- andmer-[ReCl(CO)3(PMe2Ph)2] allow the accurate determination of the very high kinetic rate constant for the isomerization and permit discussion of thermodynamic aspects of redox homogeneous chemical reactions involving species of the different redox couples arising from the anodic processes.
ELECTROANALYTICAL STUDY OF THE KINETICS OF THE FAC-MER ISOMERIZATION OF [RECL(CO)3(PME2PH)2]+ IN ACETONITRILE / Seeber, Renato; G. A., Mazzocchin; E., Roncari; U., Mazzi. - In: TRANSITION METAL CHEMISTRY. - ISSN 0340-4285. - STAMPA. - 6:(1981), pp. 123-124. [10.1007/BF00626122]
ELECTROANALYTICAL STUDY OF THE KINETICS OF THE FAC-MER ISOMERIZATION OF [RECL(CO)3(PME2PH)2]+ IN ACETONITRILE
SEEBER, Renato;
1981
Abstract
The isomerization offac-[ReCl(CO)3(PMe2Ph)2]+ to the corresponding meridional-trans isomer has been studied by electroanalytical techniques in MeCN solvent. Chronoamperometric and cyclic voltammetric data relative to the oxidation offac- andmer-[ReCl(CO)3(PMe2Ph)2] allow the accurate determination of the very high kinetic rate constant for the isomerization and permit discussion of thermodynamic aspects of redox homogeneous chemical reactions involving species of the different redox couples arising from the anodic processes.
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