Pentahalo- and mixed penta-halocuprates(II) with N-alkyl derivatives of piperazine were synthesized and charaterized by means of electronic and infrared spectra. The crystal structure of pentachloro complex was determined. The structure consists of discrete [CuCl5]3- anions with slightly distorted square-pyramidal geometry.
Spectroscopic and structural investigation on the pentachloro- and (mixedpentahalo) cuprates(II) of the N-(2-ammoniumethyl)piperazinium cation. The first case of monomeric entahalocuprate(II) having square-pyramidal structure. Crystal and molecular structure of the (N-(2-ammoniumethyl)piperazinium) pentachlorocuprate(II) dihydrate / Antolini, Luciano; Marcotrigiano, Giuseppe Onofrio; Menabue, Ledi; Pellacani, Gian Carlo. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - STAMPA. - 102:(1980), pp. 1303-1309. [10.1021/ja00524a013]
Spectroscopic and structural investigation on the pentachloro- and (mixedpentahalo) cuprates(II) of the N-(2-ammoniumethyl)piperazinium cation. The first case of monomeric entahalocuprate(II) having square-pyramidal structure. Crystal and molecular structure of the (N-(2-ammoniumethyl)piperazinium) pentachlorocuprate(II) dihydrate.
ANTOLINI, Luciano;MARCOTRIGIANO, Giuseppe Onofrio;MENABUE, Ledi;PELLACANI, Gian Carlo
1980
Abstract
Pentahalo- and mixed penta-halocuprates(II) with N-alkyl derivatives of piperazine were synthesized and charaterized by means of electronic and infrared spectra. The crystal structure of pentachloro complex was determined. The structure consists of discrete [CuCl5]3- anions with slightly distorted square-pyramidal geometry.
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