In this paper are reported structural and spectroscopic properties of (N-benzenesulphonylglycinato) triaquacopper (II) (complex I) and dipotassium bis (N-benzenesulphonylglycinato) cuprate (II) (complex II). The crystals of (I) are monoclinic, space groupP21/c,Z=4, withagr=12.736(4),b=10.292(3),c=10.402(3) Å,beta=109.41(2)° while those of complex (II) are orthorhombic, space groupPbca, witha=23.333(8),b=10.508(4),c=16.989(5) Å. In both complexes the aminoacid molecules act as bidentatevia carboxylic oxygen and the amide nitrogen atom; in (I) three water molecules complete the coordination to tetragonal pyramidal, while in (II) coordination is square planar, tetrahedrally distorted involving two ligand molecules. The structure (I) was refined to a finalR index of 0.0596 and (II) toR=0.0466.

Cobalt(II) and nickel(II) complexes of N-protected amino acids. Crystal and molecular structure of bis(Nacetylglycinato) tetraaquocobalt(II) / Menabue, Ledi; Saladini, Monica; L. P., Battaglia; Corradi, Anna; Marcotrigiano, Giuseppe Onofrio; P., Morini. - In: JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH. - ISSN 0277-8068. - STAMPA. - 17:(1987), pp. 313-319.

Cobalt(II) and nickel(II) complexes of N-protected amino acids. Crystal and molecular structure of bis(Nacetylglycinato) tetraaquocobalt(II).

MENABUE, Ledi;SALADINI, Monica;CORRADI, Anna;MARCOTRIGIANO, Giuseppe Onofrio;
1987

Abstract

In this paper are reported structural and spectroscopic properties of (N-benzenesulphonylglycinato) triaquacopper (II) (complex I) and dipotassium bis (N-benzenesulphonylglycinato) cuprate (II) (complex II). The crystals of (I) are monoclinic, space groupP21/c,Z=4, withagr=12.736(4),b=10.292(3),c=10.402(3) Å,beta=109.41(2)° while those of complex (II) are orthorhombic, space groupPbca, witha=23.333(8),b=10.508(4),c=16.989(5) Å. In both complexes the aminoacid molecules act as bidentatevia carboxylic oxygen and the amide nitrogen atom; in (I) three water molecules complete the coordination to tetragonal pyramidal, while in (II) coordination is square planar, tetrahedrally distorted involving two ligand molecules. The structure (I) was refined to a finalR index of 0.0596 and (II) toR=0.0466.
17
313
319
Cobalt(II) and nickel(II) complexes of N-protected amino acids. Crystal and molecular structure of bis(Nacetylglycinato) tetraaquocobalt(II) / Menabue, Ledi; Saladini, Monica; L. P., Battaglia; Corradi, Anna; Marcotrigiano, Giuseppe Onofrio; P., Morini. - In: JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH. - ISSN 0277-8068. - STAMPA. - 17:(1987), pp. 313-319.
Menabue, Ledi; Saladini, Monica; L. P., Battaglia; Corradi, Anna; Marcotrigiano, Giuseppe Onofrio; P., Morini
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/732657
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