Bis(N-acetyl-L-alaninato)copper(II) monohydrate and its adducts with cyclic aliphatic and aromatic amines were prepared and characterized with the aim to define the chromophore and the effect of the N-donor ligand on the N-protected aminoacid coordination behavior. The coordination geometry in the solid state for CuL2B2, where L= N-acetyl.L-alaninate and B= amine is square planar or tetragonally elongated octahedral with CuN2O2 or CuN4 chromophore.
Copper(II) complexes of peptide group containing amino acids. Bis(N-acetyl-L-alaninate)copper(II) complexes and their amine adducts / Marcotrigiano, Giuseppe Onofrio; Menabue, Ledi; Pellacani, Gian Carlo. - In: JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY. - ISSN 0022-1902. - STAMPA. - 39:(1977), pp. 1897-1901. [10.1016/0022-1902(77)80230-3]
Copper(II) complexes of peptide group containing amino acids. Bis(N-acetyl-L-alaninate)copper(II) complexes and their amine adducts.
MARCOTRIGIANO, Giuseppe Onofrio;MENABUE, Ledi;PELLACANI, Gian Carlo
1977
Abstract
Bis(N-acetyl-L-alaninato)copper(II) monohydrate and its adducts with cyclic aliphatic and aromatic amines were prepared and characterized with the aim to define the chromophore and the effect of the N-donor ligand on the N-protected aminoacid coordination behavior. The coordination geometry in the solid state for CuL2B2, where L= N-acetyl.L-alaninate and B= amine is square planar or tetragonally elongated octahedral with CuN2O2 or CuN4 chromophore.Pubblicazioni consigliate
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