The spectra (IR and NMR) of the nickel(II) and palladium(II) complexes of dithiomalonamide (Hdtma) and N,N′-diphenyldithiomalonamide (Hdpdtma) are discussed in the light of the structure of the bis(N,N′-diphenyldithiomalonamidato) nickel(II) di(N,N-dimethylformamide)solvate. The compound crystallizes in the triclinic space group P-1 (No. 2) with a=11.113(2), b=10.173(2), c=9.912(1) Å, a=74.47(6), β=108.83(7), γ=114.10(7)°, Z=1 (R=0.0495 and Rw=0.052). The crystals consist of discrete [Ni(dpdtma)2] and N,N-dimethylformamide (DMF) molecules. The nickel atom is chelated by two centrosymmetrically related ligands via sulfur atoms in an approximately squareplanar arrangement. The ligand moiety in the nickel coordination forms a π-conjugation system. The DMF solvate molecules are involved in hydrogen bonding with the NH groups of the ligand.

Nickel(II) and Palladium(II) complexes of dithiomalonamides: ligand which favor the formation of pi-conjugation systems in the coordination / L. P., Battaglia; Corradi, Anna; A., Marzotto; Menabue, Ledi; Pellacani, Gian Carlo. - In: JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH. - ISSN 0277-8068. - STAMPA. - 18:(1988), pp. 101-112. [10.1007/BF01171028]

Nickel(II) and Palladium(II) complexes of dithiomalonamides: ligand which favor the formation of pi-conjugation systems in the coordination.

CORRADI, Anna;MENABUE, Ledi;PELLACANI, Gian Carlo
1988-01-01

Abstract

The spectra (IR and NMR) of the nickel(II) and palladium(II) complexes of dithiomalonamide (Hdtma) and N,N′-diphenyldithiomalonamide (Hdpdtma) are discussed in the light of the structure of the bis(N,N′-diphenyldithiomalonamidato) nickel(II) di(N,N-dimethylformamide)solvate. The compound crystallizes in the triclinic space group P-1 (No. 2) with a=11.113(2), b=10.173(2), c=9.912(1) Å, a=74.47(6), β=108.83(7), γ=114.10(7)°, Z=1 (R=0.0495 and Rw=0.052). The crystals consist of discrete [Ni(dpdtma)2] and N,N-dimethylformamide (DMF) molecules. The nickel atom is chelated by two centrosymmetrically related ligands via sulfur atoms in an approximately squareplanar arrangement. The ligand moiety in the nickel coordination forms a π-conjugation system. The DMF solvate molecules are involved in hydrogen bonding with the NH groups of the ligand.
18
101
112
Nickel(II) and Palladium(II) complexes of dithiomalonamides: ligand which favor the formation of pi-conjugation systems in the coordination / L. P., Battaglia; Corradi, Anna; A., Marzotto; Menabue, Ledi; Pellacani, Gian Carlo. - In: JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH. - ISSN 0277-8068. - STAMPA. - 18:(1988), pp. 101-112. [10.1007/BF01171028]
L. P., Battaglia; Corradi, Anna; A., Marzotto; Menabue, Ledi; Pellacani, Gian Carlo
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/732265
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 5
  • ???jsp.display-item.citation.isi??? 5
social impact