The chapter describe the solid state polymerization of polyesters, and in particular it deals with 3.1. Introduction 3.2. Phenomena involved in solid state polymerization of polyesters 3.2.1. Possible reactions in solid state polymerization of polyesters 3.2.2. Chain mobility and diffusion of low-molecular-weight by-products 3.2.3. Kinetic and diffusion equations 3.3. Modeling solid state polymerization of polyesters 3.3.1. Effects of variables and predictions based on kinetic models 3.4. Solid state polymerization of typical polyesters 3.4.1. Poly(ethylene terephthalate) 3.4.2. Poly(butylene terephthalate) 3.4.3. Poly(ethylene naphthalate) 3.4.4. Poly(trimethylene terephthalate) 3.4.5. Poly(l-lactic acid) 3.5. Conclusions
Kinetic Aspects of Polyester Solid State Polymerization / Pilati, F., M., T. - In: Solid-State Polymerization / C. D. Papaspyrides and S. N. Vouyiouka, Haibing Zhang and Saleh A. Jabarin, F. Pilati and M. Toselli, Rudolf Pfaendner, Tokimitsu Ikawa, Kevin C. Seavey and Y. A. Liu, S. A. Wadekar, U. S. Agarwal, W. H. Boon, and V. M. Nadkarni. - STAMPA. - New Jersey : John Wiley & Sons, Inc., 2009. - ISBN 9780470084182. - pp. 67-122 [10.1002/9780470451830.ch3]
Kinetic Aspects of Polyester Solid State Polymerization
PILATI, Francesco;
2009
Abstract
The chapter describe the solid state polymerization of polyesters, and in particular it deals with 3.1. Introduction 3.2. Phenomena involved in solid state polymerization of polyesters 3.2.1. Possible reactions in solid state polymerization of polyesters 3.2.2. Chain mobility and diffusion of low-molecular-weight by-products 3.2.3. Kinetic and diffusion equations 3.3. Modeling solid state polymerization of polyesters 3.3.1. Effects of variables and predictions based on kinetic models 3.4. Solid state polymerization of typical polyesters 3.4.1. Poly(ethylene terephthalate) 3.4.2. Poly(butylene terephthalate) 3.4.3. Poly(ethylene naphthalate) 3.4.4. Poly(trimethylene terephthalate) 3.4.5. Poly(l-lactic acid) 3.5. Conclusions
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