Intramolecular participation of carbon-carbon double bonds and hydroxy-groups can occur when alcohols are treted with complexes derived from dimethyl sulphide and N-halogenosuccinimide. Neighbouring group participation is more common in the reactions in which N-bromosuccinimide rather than N-chlorosuccinimide is employed, the results suggest caution when the alcohol to halide conversion is attempted in certain polyfunctional molecules.
Some Anomalous Products from the Attempted Halogenation of Unsaturated Alcohols by the Complex from Dimethyl Sulphide and N-Halogenosuccinimide / Bellesia, Franco; R., Grandi; Pagnoni, Ugo Maria; R., Trave. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - STAMPA. - 1:(1979), pp. 851-855.
Some Anomalous Products from the Attempted Halogenation of Unsaturated Alcohols by the Complex from Dimethyl Sulphide and N-Halogenosuccinimide
BELLESIA, Franco;PAGNONI, Ugo Maria;
1979
Abstract
Intramolecular participation of carbon-carbon double bonds and hydroxy-groups can occur when alcohols are treted with complexes derived from dimethyl sulphide and N-halogenosuccinimide. Neighbouring group participation is more common in the reactions in which N-bromosuccinimide rather than N-chlorosuccinimide is employed, the results suggest caution when the alcohol to halide conversion is attempted in certain polyfunctional molecules.Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris