In treating olefinic acyl-p-tosylhydrazides with reducing, acidic or basic agents, the reactivity of carbon-nitrogen double bond towards hydride ion is drastically reduced in conjugated acyl substrates. Under severe reaction condition tars and many by-products are formed. In alkaline condition alfa-beta unsaturated substrates were almost unchanged and ring closure was never observed.
Base and Acid Decomposition of Unsatarated 1-Acyl-2-Tosylhydrazines / Bellesia, Franco; R., Grandi; Pagnoni, Ugo Maria; R., Trave. - In: GAZZETTA CHIMICA ITALIANA. - ISSN 0016-5603. - STAMPA. - 111:(1981), pp. 511-513.
Base and Acid Decomposition of Unsatarated 1-Acyl-2-Tosylhydrazines.
BELLESIA, Franco;PAGNONI, Ugo Maria;
1981
Abstract
In treating olefinic acyl-p-tosylhydrazides with reducing, acidic or basic agents, the reactivity of carbon-nitrogen double bond towards hydride ion is drastically reduced in conjugated acyl substrates. Under severe reaction condition tars and many by-products are formed. In alkaline condition alfa-beta unsaturated substrates were almost unchanged and ring closure was never observed.
Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
