In situ formation of MnCl4 by reaction of MnO2 with ClSiMe3 or AcCl followed by reaction with a ketone gives the α-chloro ketone. A CH2 group is attacked in preference to a Me group; steric factors limit the chlorination of CH groups.
The chlorination of ketones with manganese(IV) chloride / Bellesia, Franco; Ghelfi, Franco; Pagnoni, Ugo Maria; Pinetti, Adriano. - In: JOURNAL OF CHEMICAL RESEARCH. - ISSN 0308-2350. - STAMPA. - -:(1990), pp. 188-189.
The chlorination of ketones with manganese(IV) chloride
BELLESIA, Franco;GHELFI, Franco;PAGNONI, Ugo Maria;PINETTI, Adriano
1990
Abstract
In situ formation of MnCl4 by reaction of MnO2 with ClSiMe3 or AcCl followed by reaction with a ketone gives the α-chloro ketone. A CH2 group is attacked in preference to a Me group; steric factors limit the chlorination of CH groups.
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