The synthesis of a series of heterometallic rings and chains is reported. The family is based on theoctanuclear cages of general formula [H2NR2][M7M9F8(O2CR9)16], where M is a trivalent metal(Cr, Fe, V, Al, Ga or In), M9 is a divalent metal (Mn, Fe, Co, Ni, Mg, Zn, Cd), R is a linear alkylchain and O2CR9 is one of around twenty carboxylates. Other members of the family withnonametallic and decametallic cores are described, and some new physics is outlined, includinginitial investigations of the proposed application of {Cr7Ni} rings as Qubits in quantuminformation processing.

A Ring Cycle: Studies of Heterometallic Wheels / AFFRONTE, Marco; S., Carretta; G. A., Timco; R. E. P., Winpenny. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 0:18(2007), pp. 1789-1797. [10.1039/b615543j]

A Ring Cycle: Studies of Heterometallic Wheels

AFFRONTE, Marco;
2007

Abstract

The synthesis of a series of heterometallic rings and chains is reported. The family is based on theoctanuclear cages of general formula [H2NR2][M7M9F8(O2CR9)16], where M is a trivalent metal(Cr, Fe, V, Al, Ga or In), M9 is a divalent metal (Mn, Fe, Co, Ni, Mg, Zn, Cd), R is a linear alkylchain and O2CR9 is one of around twenty carboxylates. Other members of the family withnonametallic and decametallic cores are described, and some new physics is outlined, includinginitial investigations of the proposed application of {Cr7Ni} rings as Qubits in quantuminformation processing.
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A Ring Cycle: Studies of Heterometallic Wheels / AFFRONTE, Marco; S., Carretta; G. A., Timco; R. E. P., Winpenny. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 0:18(2007), pp. 1789-1797. [10.1039/b615543j]
Affronte, Marco; S., Carretta; G. A., Timco; R. E. P., Winpenny
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/639990
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