A configurational and conformational study of N-substituted, N-acetyl and N-sulfonylaziridines carboxylates has been performed by 1H, 13C 17O and 15N NMR spectroscopy. The presence of acetyl and sulfonyl groups on the ring nitrogen atom seems to reduce greatly the configurational stability at nitrogen.
Invertomers at nitrogen in aziridine carboxylates by multinuclear (H-1, C-13, O-17 and N-15) NMR study / Forni, Arrigo; Moretti, Irene; Mucci, Adele; Prati, Fabio; Schenetti, Luisa. - In: KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII. - ISSN 0132-6244. - STAMPA. - 9:(1995), pp. 1226-1234. [10.1007/BF01165053]
Invertomers at nitrogen in aziridine carboxylates by multinuclear (H-1, C-13, O-17 and N-15) NMR study
FORNI, Arrigo;MORETTI, Irene;MUCCI, Adele;PRATI, Fabio;SCHENETTI, Luisa
1995
Abstract
A configurational and conformational study of N-substituted, N-acetyl and N-sulfonylaziridines carboxylates has been performed by 1H, 13C 17O and 15N NMR spectroscopy. The presence of acetyl and sulfonyl groups on the ring nitrogen atom seems to reduce greatly the configurational stability at nitrogen.
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