The first asym. synthesis of trans optically active (+) C2 1,3-bisarylepoxide of calix[4]arene I in excellent chem. yield and >99% ee, and its enantiospecific conversion to the corresponding bis-dioxolane II is reported.
Novel Chiral Calix[4]arenes by Direct Asymmetric Epoxidation Reaction / C., Bonini; L., Chiummiento; M., Funicello; M. T., Lopardo; P., Lupattelli; A., Laurita; Cornia, Andrea. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 73:11(2008), pp. 4233-4236. [10.1021/jo800301m]
Novel Chiral Calix[4]arenes by Direct Asymmetric Epoxidation Reaction
CORNIA, Andrea
2008
Abstract
The first asym. synthesis of trans optically active (+) C2 1,3-bisarylepoxide of calix[4]arene I in excellent chem. yield and >99% ee, and its enantiospecific conversion to the corresponding bis-dioxolane II is reported.
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