A simple empirical formula enables the quantitative description of chiral autocatalysis. This formula was used for the prediction of the number of consecutive autocatalytic reaction cycles needed to obtain a high enantiomeric excess without chiral auxiliary or an asymmetric physical field (absolute enantioselective synthesis). The results show, that even less selective Soai-type systems can be used for absolute enantioselective synthesis, which, therefore, appears to be a fairly general phenomenon. (c) 2006 Published by Elsevier Ltd.

Generalization possibilities of autocatalytic absolute enantioselective synthesis / Micskei, K; Maioli, Marco; Zucchi, Claudia; Caglioti, L; Palyi, Gyula. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 17:21(2006), pp. 2960-2962. [10.1016/j.tetasy.2006.11.016]

Generalization possibilities of autocatalytic absolute enantioselective synthesis

MAIOLI, Marco;ZUCCHI, Claudia;PALYI, Gyula
2006

Abstract

A simple empirical formula enables the quantitative description of chiral autocatalysis. This formula was used for the prediction of the number of consecutive autocatalytic reaction cycles needed to obtain a high enantiomeric excess without chiral auxiliary or an asymmetric physical field (absolute enantioselective synthesis). The results show, that even less selective Soai-type systems can be used for absolute enantioselective synthesis, which, therefore, appears to be a fairly general phenomenon. (c) 2006 Published by Elsevier Ltd.
2006
17
21
2960
2962
Generalization possibilities of autocatalytic absolute enantioselective synthesis / Micskei, K; Maioli, Marco; Zucchi, Claudia; Caglioti, L; Palyi, Gyula. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 17:21(2006), pp. 2960-2962. [10.1016/j.tetasy.2006.11.016]
Micskei, K; Maioli, Marco; Zucchi, Claudia; Caglioti, L; Palyi, Gyula
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/612113
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 29
  • ???jsp.display-item.citation.isi??? 28
social impact