The electronic effect of some meta- or para-substituents on the reduction of the title compounds has been investigated. The reversible reduction potential values of these compounds have been evaluated by cyclic voltammetry at a mercury electrode in 0.1 M tetraethylammoniumtetrafluoroborate, dimethylsulfoxide solutions. The substituent effect depends on both its nature and its position. The reduction potential Values of the derivatives studied have been correlated with the Hammett substituent constants.

Substituent effect on the redox potential of substituted(aryl)(2-nitrobenzo [b]thiophen-3-yl) amines / B., Cosimelli; D., Spinelli; F., Costanzo; D., Tonelli; L., Lamartina; M. C., Sarvà; Seeber, Renato. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 57(2001), pp. 1957-1960. [10.1016/S0040-4020(00)01166-2]

Substituent effect on the redox potential of substituted(aryl)(2-nitrobenzo [b]thiophen-3-yl) amines

SEEBER, Renato
2001

Abstract

The electronic effect of some meta- or para-substituents on the reduction of the title compounds has been investigated. The reversible reduction potential values of these compounds have been evaluated by cyclic voltammetry at a mercury electrode in 0.1 M tetraethylammoniumtetrafluoroborate, dimethylsulfoxide solutions. The substituent effect depends on both its nature and its position. The reduction potential Values of the derivatives studied have been correlated with the Hammett substituent constants.
57
1957
1960
Substituent effect on the redox potential of substituted(aryl)(2-nitrobenzo [b]thiophen-3-yl) amines / B., Cosimelli; D., Spinelli; F., Costanzo; D., Tonelli; L., Lamartina; M. C., Sarvà; Seeber, Renato. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 57(2001), pp. 1957-1960. [10.1016/S0040-4020(00)01166-2]
B., Cosimelli; D., Spinelli; F., Costanzo; D., Tonelli; L., Lamartina; M. C., Sarvà; Seeber, Renato
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/609864
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