The Karstedt-catalyzed hydrosilylation reaction used in curing of silicone release coatings was investigated using first-principle quantum mechanical techniques (density functional theory) as well as semiempirical methods to estimate solubility parameters. The results we obtain for the catalytic cycle indicate, in agreement with experimental results, that hydrosilylation occurs easily at room temperature. The detailed mechanism we suggest contains the key features of the models previously proposed in the literature by Lewis and Chalk-Harrod and adds quantitative estimates of reaction energies and barriers. On the basis of the energy profile for the catalytic cycle in the presence of inhibitor molecules and on solubility parameters for the species involved in the reaction, we conclude that the role of the inhibitors we considered is to phase-separate the catalyst from the substrate. The reaction is thus quenched by introducing a microscopic second phase that interferes with the homogeneous reaction.
Heterogeneous Inhibition of Homogeneous Reactions: Karstedt Catalyzed Hydrosilylation / Faglioni, Francesco; M., Blanco; W. A., GODDARD III; D., Saunders. - In: JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL. - ISSN 1520-6106. - STAMPA. - 106(2002), pp. 1714-1721.
Data di pubblicazione: | 2002 |
Titolo: | Heterogeneous Inhibition of Homogeneous Reactions: Karstedt Catalyzed Hydrosilylation |
Autore/i: | Faglioni, Francesco; M., Blanco; W. A., GODDARD III; D., Saunders |
Autore/i UNIMORE: | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/jp0128933 |
Rivista: | |
Volume: | 106 |
Pagina iniziale: | 1714 |
Pagina finale: | 1721 |
Codice identificativo ISI: | WOS:000173981900029 |
Codice identificativo Scopus: | 2-s2.0-0037149172 |
Citazione: | Heterogeneous Inhibition of Homogeneous Reactions: Karstedt Catalyzed Hydrosilylation / Faglioni, Francesco; M., Blanco; W. A., GODDARD III; D., Saunders. - In: JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL. - ISSN 1520-6106. - STAMPA. - 106(2002), pp. 1714-1721. |
Tipologia | Articolo su rivista |
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