Herein we report thesynthesis and structure of a decametallic mixed-valent Mnsupertetrahedron with the ligand 2-amino-2-methyl-1,3-propanediol(ampH2); this cluster displays dominant ferromagneticexchange and a spin ground state of S=22. Furthermore,we show that the magnetic behavior of the compound isparticularly appealing in view of its possible application as anefficient low-temperature magnetic refrigerant.
A ferromagnetic mixed-valent Mn supertetrahedron: towards low-temperature magnetic refrigeration / M., Manoli; R. D. L., Johnstone; S., Parsons; M., Murrie; Affronte, Marco; M. EVANGELISTI AND E. K., Brechin. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 46:24(2007), pp. 4456-4460. [10.1002/anie.200701027]
A ferromagnetic mixed-valent Mn supertetrahedron: towards low-temperature magnetic refrigeration
AFFRONTE, Marco;
2007
Abstract
Herein we report thesynthesis and structure of a decametallic mixed-valent Mnsupertetrahedron with the ligand 2-amino-2-methyl-1,3-propanediol(ampH2); this cluster displays dominant ferromagneticexchange and a spin ground state of S=22. Furthermore,we show that the magnetic behavior of the compound isparticularly appealing in view of its possible application as anefficient low-temperature magnetic refrigerant.
Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
