Herein we report thesynthesis and structure of a decametallic mixed-valent Mnsupertetrahedron with the ligand 2-amino-2-methyl-1,3-propanediol(ampH2); this cluster displays dominant ferromagneticexchange and a spin ground state of S=22. Furthermore,we show that the magnetic behavior of the compound isparticularly appealing in view of its possible application as anefficient low-temperature magnetic refrigerant.

A ferromagnetic mixed-valent Mn supertetrahedron: towards low-temperature magnetic refrigeration / M., Manoli; R. D. L., Johnstone; S., Parsons; M., Murrie; Affronte, Marco; M. EVANGELISTI AND E. K., Brechin. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 46:24(2007), pp. 4456-4460. [10.1002/anie.200701027]

A ferromagnetic mixed-valent Mn supertetrahedron: towards low-temperature magnetic refrigeration

AFFRONTE, Marco;
2007

Abstract

Herein we report thesynthesis and structure of a decametallic mixed-valent Mnsupertetrahedron with the ligand 2-amino-2-methyl-1,3-propanediol(ampH2); this cluster displays dominant ferromagneticexchange and a spin ground state of S=22. Furthermore,we show that the magnetic behavior of the compound isparticularly appealing in view of its possible application as anefficient low-temperature magnetic refrigerant.
46
24
4456
4460
A ferromagnetic mixed-valent Mn supertetrahedron: towards low-temperature magnetic refrigeration / M., Manoli; R. D. L., Johnstone; S., Parsons; M., Murrie; Affronte, Marco; M. EVANGELISTI AND E. K., Brechin. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 46:24(2007), pp. 4456-4460. [10.1002/anie.200701027]
M., Manoli; R. D. L., Johnstone; S., Parsons; M., Murrie; Affronte, Marco; M. EVANGELISTI AND E. K., Brechin
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/608831
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