Binary copper(II) compounds of N-tosylvalinate of formula [Cu(tsvalO)2(H2O)2]4H2O and [Cu(tsvalO)2(H2O)2(MeOH)2] were separated. The structure of the latter consists of discrete [Cu(tsvalO)2(H2O)2(MeOH)2] units in which the copper ion, lying on the symmetry centre, is surrounded by two carboxylic oxygens and two water molecules centrosymmetrically related. Two methanol molecules complete the co-ordination which is elongated tetragonal bipyramidal. The spectroscopic properties are consistent with a CuO6 chromophore. (...)
Spectroscopic, magnetic, and structural properties of diaquadimethanolbis-(N-tosylvalinato)copper(II) and its 2,2'-bipyridine adduct / L. P., Battaglia; Corradi, Anna; Menabue, Ledi; Saladini, Monica; Sola, Marco. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - STAMPA. - (1987), pp. 1333-1339.
Spectroscopic, magnetic, and structural properties of diaquadimethanolbis-(N-tosylvalinato)copper(II) and its 2,2'-bipyridine adduct
CORRADI, Anna;MENABUE, Ledi;SALADINI, Monica;SOLA, Marco
1987
Abstract
Binary copper(II) compounds of N-tosylvalinate of formula [Cu(tsvalO)2(H2O)2]4H2O and [Cu(tsvalO)2(H2O)2(MeOH)2] were separated. The structure of the latter consists of discrete [Cu(tsvalO)2(H2O)2(MeOH)2] units in which the copper ion, lying on the symmetry centre, is surrounded by two carboxylic oxygens and two water molecules centrosymmetrically related. Two methanol molecules complete the co-ordination which is elongated tetragonal bipyramidal. The spectroscopic properties are consistent with a CuO6 chromophore. (...)
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