The synthesis and chemical polymerization of a thiophene disubstituted with an alkylic and an u-bromine functionalized oligomethylenicchain is described. The obtained polymer, namely the poly[3-hexyl-4-(6-bromohexyl)thiophene], is completely soluble in common organicsolvents and its structural, thermal and chemical–physical properties are compared with those of a ‘conventional’ bromohexyl 3-substitutedpolythiophene. The new polymer may be considered as a key-intermediate for the synthesis of multifunctional soluble polythiophenes sinceits self-plastifying feature may permit the insertion on the polymeric side-chains, by simple post-polymerization functionalization reactions,of sterically demanding or strongly interacting functional groups, without final solubility being compromised.q 2004 Elsevier Ltd. All rights reserved.

Poly[3-hexyl-4-(6-bromohexyl)thiophene]: A key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes / P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca. - In: POLYMER. - ISSN 0032-3861. - STAMPA. - 45:26(2004), pp. 8629-8637. [10.1016/j.polymer.2004.10.069]

Poly[3-hexyl-4-(6-bromohexyl)thiophene]: A key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes

PARENTI, Francesca
2004

Abstract

The synthesis and chemical polymerization of a thiophene disubstituted with an alkylic and an u-bromine functionalized oligomethylenicchain is described. The obtained polymer, namely the poly[3-hexyl-4-(6-bromohexyl)thiophene], is completely soluble in common organicsolvents and its structural, thermal and chemical–physical properties are compared with those of a ‘conventional’ bromohexyl 3-substitutedpolythiophene. The new polymer may be considered as a key-intermediate for the synthesis of multifunctional soluble polythiophenes sinceits self-plastifying feature may permit the insertion on the polymeric side-chains, by simple post-polymerization functionalization reactions,of sterically demanding or strongly interacting functional groups, without final solubility being compromised.q 2004 Elsevier Ltd. All rights reserved.
2004
45
26
8629
8637
Poly[3-hexyl-4-(6-bromohexyl)thiophene]: A key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes / P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca. - In: POLYMER. - ISSN 0032-3861. - STAMPA. - 45:26(2004), pp. 8629-8637. [10.1016/j.polymer.2004.10.069]
P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca
File in questo prodotto:
File Dimensione Formato  
Polymer (2004).pdf

Accesso riservato

Tipologia: Versione dell'autore revisionata e accettata per la pubblicazione
Dimensione 194.38 kB
Formato Adobe PDF
194.38 kB Adobe PDF   Visualizza/Apri   Richiedi una copia
Pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/585379
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 6
  • ???jsp.display-item.citation.isi??? 7
social impact