EnglishThe synthesis and chemical polymerization of a thiophene disubstituted with an alkylic and an u-bromine functionalized oligomethylenicchain is described. The obtained polymer, namely the poly[3-hexyl-4-(6-bromohexyl)thiophene], is completely soluble in common organicsolvents and its structural, thermal and chemical–physical properties are compared with those of a ‘conventional’ bromohexyl 3-substitutedpolythiophene. The new polymer may be considered as a key-intermediate for the synthesis of multifunctional soluble polythiophenes sinceits self-plastifying feature may permit the insertion on the polymeric side-chains, by simple post-polymerization functionalization reactions,of sterically demanding or strongly interacting functional groups, without final solubility being compromised.q 2004 Elsevier Ltd. All rights reserved.
"Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes" / P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca. - In: POLYMER. - ISSN 0032-3861. - STAMPA. - 45(2004), pp. 8629-8637.
| Data di pubblicazione: | 2004 | |
| Titolo: | "Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes" | |
| Autore/i: | P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca | |
| Autore/i UNIMORE: | ||
| Rivista: | ||
| Volume: | 45 | |
| Pagina iniziale: | 8629 | |
| Pagina finale: | 8637 | |
| Codice identificativo ISI: | WOS:000225508100001 | |
| Codice identificativo Scopus: | 2-s2.0-9244249175 | |
| Citazione: | "Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes" / P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca. - In: POLYMER. - ISSN 0032-3861. - STAMPA. - 45(2004), pp. 8629-8637. | |
| Tipologia | Articolo su rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | |
|---|---|---|---|
| Polymer (2004).pdf | Post-print dell'autore (bozza post referaggio) | Administrator Richiedi una copia |
Pubblicazioni consigliate
http://hdl.handle.net/11380/585379
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
Copyright © 2021