"Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes"

Costa Bizzarri, P.; Lanzi, M.; Paganin, L.; Caretti, D.; Parenti, Francesca

The synthesis and chemical polymerization of a thiophene disubstituted with an alkylic and an u-bromine functionalized oligomethylenicchain is described. The obtained polymer, namely the poly[3-hexyl-4-(6-bromohexyl)thiophene], is completely soluble in common organicsolvents and its structural, thermal and chemical–physical properties are compared with those of a ‘conventional’ bromohexyl 3-substitutedpolythiophene. The new polymer may be considered as a key-intermediate for the synthesis of multifunctional soluble polythiophenes sinceits self-plastifying feature may permit the insertion on the polymeric side-chains, by simple post-polymerization functionalization reactions,of sterically demanding or strongly interacting functional groups, without final solubility being compromised.q 2004 Elsevier Ltd. All rights reserved.

"Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes" / P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca. - In: POLYMER. - ISSN 0032-3861. - STAMPA. - 45(2004), pp. 8629-8637.

Data di pubblicazione:	2004
Titolo:	"Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes"
Autore/i:	P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca
Autore/i UNIMORE:	P. COSTA BIZZARRI M. LANZI L. PAGANIN D. CARETTI PARENTI, Francesca mostra contributor esterni nascondi contributor esterni
Rivista:	POLYMER
Volume:	45
Pagina iniziale:	8629
Pagina finale:	8637
Codice identificativo ISI:	WOS:000225508100001
Codice identificativo Scopus:	2-s2.0-9244249175
Citazione:	"Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes" / P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca. - In: POLYMER. - ISSN 0032-3861. - STAMPA. - 45(2004), pp. 8629-8637.
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http://hdl.handle.net/11380/585379

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