The synthesis and chemical polymerization of a thiophene disubstituted with an alkylic and an u-bromine functionalized oligomethylenicchain is described. The obtained polymer, namely the poly[3-hexyl-4-(6-bromohexyl)thiophene], is completely soluble in common organicsolvents and its structural, thermal and chemical–physical properties are compared with those of a ‘conventional’ bromohexyl 3-substitutedpolythiophene. The new polymer may be considered as a key-intermediate for the synthesis of multifunctional soluble polythiophenes sinceits self-plastifying feature may permit the insertion on the polymeric side-chains, by simple post-polymerization functionalization reactions,of sterically demanding or strongly interacting functional groups, without final solubility being compromised.q 2004 Elsevier Ltd. All rights reserved.
"Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes" / P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca. - In: POLYMER. - ISSN 0032-3861. - STAMPA. - 45(2004), pp. 8629-8637.
Data di pubblicazione: | 2004 |
Titolo: | "Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes" |
Autore/i: | P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca |
Autore/i UNIMORE: | |
Rivista: | |
Volume: | 45 |
Pagina iniziale: | 8629 |
Pagina finale: | 8637 |
Codice identificativo ISI: | WOS:000225508100001 |
Codice identificativo Scopus: | 2-s2.0-9244249175 |
Citazione: | "Poly[3-hexyl-4-(6-bromohexyl)thiophene]: a key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes" / P., COSTA BIZZARRI; M., Lanzi; L., Paganin; D., Caretti; Parenti, Francesca. - In: POLYMER. - ISSN 0032-3861. - STAMPA. - 45(2004), pp. 8629-8637. |
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