A new series of manganese(III), cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) complexes with monomethylsubstituted dithiocarbamates as ligands has been synthesized and studied. Their structures are discussed in relation to their spectroscopic, magnetic and thermal properties. The dithio-ligands exhibit bidentate behaviour acting as S,S donors in all the complexes. In the far i.r. region particular attention is paid to a comparison of the spectra of the octahedral complexes with those of the other metal derivatives (1 2 metal to ligand molar ratio). The e.s.r. spectra are indicative of aD 2h symmetry in the cobalt(II) complexes.

Transition metal complexes with 2-methyl, 3-methyl and 4-methyl-piperidine dithiocarbamate as ligands / Zannini, Paolo; FABRETTI A., C; Franchini, Giancarlo; Preti, C; Tosi, G. - In: TRANSITION METAL CHEMISTRY. - ISSN 0082-5921. - STAMPA. - 10(1985), pp. 284-287.

Transition metal complexes with 2-methyl, 3-methyl and 4-methyl-piperidine dithiocarbamate as ligands

ZANNINI, Paolo;FRANCHINI, Giancarlo;
1985

Abstract

A new series of manganese(III), cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) complexes with monomethylsubstituted dithiocarbamates as ligands has been synthesized and studied. Their structures are discussed in relation to their spectroscopic, magnetic and thermal properties. The dithio-ligands exhibit bidentate behaviour acting as S,S donors in all the complexes. In the far i.r. region particular attention is paid to a comparison of the spectra of the octahedral complexes with those of the other metal derivatives (1 2 metal to ligand molar ratio). The e.s.r. spectra are indicative of aD 2h symmetry in the cobalt(II) complexes.
10
284
287
Transition metal complexes with 2-methyl, 3-methyl and 4-methyl-piperidine dithiocarbamate as ligands / Zannini, Paolo; FABRETTI A., C; Franchini, Giancarlo; Preti, C; Tosi, G. - In: TRANSITION METAL CHEMISTRY. - ISSN 0082-5921. - STAMPA. - 10(1985), pp. 284-287.
Zannini, Paolo; FABRETTI A., C; Franchini, Giancarlo; Preti, C; Tosi, G
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/460757
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 21
  • ???jsp.display-item.citation.isi??? 22
social impact