Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiornorpholine-4-carbodithioate complexes of chromium(III), manganese(III), tin(II) and lead(II) are prepared and characterized by chemical analyses, spectroscopic methods (I.R. and electronic spectra), magnetic susceptibilities, conductivity measurements and mass spectra. The complexes are of the type M(R2dtc)n, where n is the oxidation number of the metal ion. Where possible a tentative stereochemistry of the complexes is discussed on the basis of the results obtained. In all the complexes the dithiocarbamate ligands show bidentate behaviour.
Investigations on chromium (III), manganese (II), tin (II) and lead (II) dithiocarbamate complexes / C., Preti; G., Tosi; Zannini, Paolo. - In: JOURNAL OF MOLECULAR STRUCTURE. - ISSN 0022-2860. - STAMPA. - 65:(1980), pp. 283-292.
Investigations on chromium (III), manganese (II), tin (II) and lead (II) dithiocarbamate complexes
ZANNINI, Paolo
1980
Abstract
Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiornorpholine-4-carbodithioate complexes of chromium(III), manganese(III), tin(II) and lead(II) are prepared and characterized by chemical analyses, spectroscopic methods (I.R. and electronic spectra), magnetic susceptibilities, conductivity measurements and mass spectra. The complexes are of the type M(R2dtc)n, where n is the oxidation number of the metal ion. Where possible a tentative stereochemistry of the complexes is discussed on the basis of the results obtained. In all the complexes the dithiocarbamate ligands show bidentate behaviour.
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