Piperidine carbodithioate (Pipdtc), morpholine-4-(Morphdtc), thiomorpholine-4-(Timdtc), piperazine-4-(Pzdtc) and N-methylpiperazine-4-carbodithioate (CH3-Pzdtc) complexes of ruthenium have been prepared and characterized by spectroscopic methods (IR and electronic spectra), magnetic susceptibilities and conductivity measurements. Where possible a tentative stereochemistry of the complexes is discussed based upon the obtained results. The dithiocarbamate ligands show in all the complexes a bidentate behaviour. A distorted octahedral geometry is proposed for the water containing 1:2 derivatives: in fact from a detailed analysis of the infrared spectra the water resulted always coordinated to the metal. The Pzdtc 1:2 derivative resulted polymeric octahedral with the NH group of the heterocyclic ring involved in the coordination.

Synthesis and characterization of ruthenium dithiocarbamate complexes / C., Preti; G., Tosi; Zannini, Paolo. - In: JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY. - ISSN 0022-1902. - STAMPA. - 41:(1979), pp. 485-488.

Synthesis and characterization of ruthenium dithiocarbamate complexes

ZANNINI, Paolo
1979

Abstract

Piperidine carbodithioate (Pipdtc), morpholine-4-(Morphdtc), thiomorpholine-4-(Timdtc), piperazine-4-(Pzdtc) and N-methylpiperazine-4-carbodithioate (CH3-Pzdtc) complexes of ruthenium have been prepared and characterized by spectroscopic methods (IR and electronic spectra), magnetic susceptibilities and conductivity measurements. Where possible a tentative stereochemistry of the complexes is discussed based upon the obtained results. The dithiocarbamate ligands show in all the complexes a bidentate behaviour. A distorted octahedral geometry is proposed for the water containing 1:2 derivatives: in fact from a detailed analysis of the infrared spectra the water resulted always coordinated to the metal. The Pzdtc 1:2 derivative resulted polymeric octahedral with the NH group of the heterocyclic ring involved in the coordination.
1979
41
485
488
Synthesis and characterization of ruthenium dithiocarbamate complexes / C., Preti; G., Tosi; Zannini, Paolo. - In: JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY. - ISSN 0022-1902. - STAMPA. - 41:(1979), pp. 485-488.
C., Preti; G., Tosi; Zannini, Paolo
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/460737
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 29
  • ???jsp.display-item.citation.isi??? 42
social impact