Optically-active sulphenyl or sulphonyl fluorohydrins were obtained by reduction of ketones with baker's yeast or by enzymatic resolution of their racemic esters using Candida cylindracea lipase. Crystallization of partially optically fluorohydrins gave enantiomerically pure forms. The enantioselectivity of the enzymatic reaction is affected by steric requirements of the substituents

Biotransformations of Fluorinated Sulphenyl and Sulphonyl Compounds / Bucciarelli, Maria; Forni, Arrigo; Moretti, Irene; Prati, Fabio; Torre, Giovanni; G., Resnati; P., Bravo. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 45:(1989), pp. 7505-7505.

Biotransformations of Fluorinated Sulphenyl and Sulphonyl Compounds

BUCCIARELLI, Maria;FORNI, Arrigo;MORETTI, Irene;PRATI, Fabio;TORRE, Giovanni;
1989

Abstract

Optically-active sulphenyl or sulphonyl fluorohydrins were obtained by reduction of ketones with baker's yeast or by enzymatic resolution of their racemic esters using Candida cylindracea lipase. Crystallization of partially optically fluorohydrins gave enantiomerically pure forms. The enantioselectivity of the enzymatic reaction is affected by steric requirements of the substituents
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7505
7505
Biotransformations of Fluorinated Sulphenyl and Sulphonyl Compounds / Bucciarelli, Maria; Forni, Arrigo; Moretti, Irene; Prati, Fabio; Torre, Giovanni; G., Resnati; P., Bravo. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 45:(1989), pp. 7505-7505.
Bucciarelli, Maria; Forni, Arrigo; Moretti, Irene; Prati, Fabio; Torre, Giovanni; G., Resnati; P., Bravo
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/457194
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