X-Ray analysis of the (E)-1-cloro-2-methoxycarbamoylaziridine shows that the absolute configuration at the chiral centers is (-)-(1R,2R); this enables us to assign the S configuration to the chiral nitrogen atom in the related compound (+)-1-chloro-2,2-bismethoxycarbonylaziridine.
Derivatives of Optically Active 1-Chloro-2,2-bismethoxycarbonylaziridine: Absolute Configuration and X-Ray Molecular Structure of (-)-(E)-1-Chloro-2- methoxycarbonyl- 2-methylcarbamoylaziridine / Antolini, Luciano; Bucciarelli, Maria; Forni, Arrigo; Moretti, Irene; Prati, Fabio. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 15:(1991), pp. 538-538.
Derivatives of Optically Active 1-Chloro-2,2-bismethoxycarbonylaziridine: Absolute Configuration and X-Ray Molecular Structure of (-)-(E)-1-Chloro-2- methoxycarbonyl- 2-methylcarbamoylaziridine.
ANTOLINI, Luciano;BUCCIARELLI, Maria;FORNI, Arrigo;MORETTI, Irene;PRATI, Fabio
1991
Abstract
X-Ray analysis of the (E)-1-cloro-2-methoxycarbamoylaziridine shows that the absolute configuration at the chiral centers is (-)-(1R,2R); this enables us to assign the S configuration to the chiral nitrogen atom in the related compound (+)-1-chloro-2,2-bismethoxycarbonylaziridine.
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