The synthesis of optically activew cis and trans 1-chloro-2-methoxycarbonyl-2-methylcarbamoylaziridine is described and their relative stability determined by thermal equilibration. The crystal structure of cis aziridine was determined by X-ray diffraction analysis and compared qith the of the trans isomer. The chiroptical properties and configurational correlations with the parent compound 1-chloro-2,2-bismethoxyzarbonylaziridine are reported
Optically Active cis- and trans-1-Chloro-2-methoxycarbonyl-2-methylcarbamoyl-aziridines. Stereochemical Properties / Antolini, Luciano; Bucciarelli, Maria; Forni, Arrigo; Moretti, Irene; Prati, Fabio; Torre, Giovanni. - In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS II. - ISSN 0300-9580. - STAMPA. - 12:(1992), pp. 959-959.
Optically Active cis- and trans-1-Chloro-2-methoxycarbonyl-2-methylcarbamoyl-aziridines. Stereochemical Properties
ANTOLINI, Luciano;BUCCIARELLI, Maria;FORNI, Arrigo;MORETTI, Irene;PRATI, Fabio;TORRE, Giovanni
1992
Abstract
The synthesis of optically activew cis and trans 1-chloro-2-methoxycarbonyl-2-methylcarbamoylaziridine is described and their relative stability determined by thermal equilibration. The crystal structure of cis aziridine was determined by X-ray diffraction analysis and compared qith the of the trans isomer. The chiroptical properties and configurational correlations with the parent compound 1-chloro-2,2-bismethoxyzarbonylaziridine are reported
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