Some imidazo[2,1-b]thiazoles have been subjected to a 1H n.m.r. investigation. The aromatic character of this ring system, in connection with proton shielding, has been tested with coupled Hartree–Fock calculations of ring current effects, and it seems that the main differences in the chemical shifts relative to the single ring heterocycles are due to this kind of perturbation. A long-range coupling constant over six bonds has also been observed which implies a coupling mechanism involving the sulphur atom.

Some imidazo[2,1-b]thiazoles have been subjected to a 1H n.m.r. investigation. The aromatic character of this ring system, in connection with proton shielding, has been tested with coupled Hartree-Fock calculations of ring current effects, and it seems that the main differences in the chemical shifts relative to the single ring heterocycles are due to this kind of perturbation. A long-range coupling constant over six bonds has also been observed which implies a coupling mechanism involving the sulphur atom.

1H Nuclear Magnetic Resonance Spectra of the Imidazo[2,1-b]thiazole System / L., Marchetti; L., Pentimalli; Lazzeretti, Paolo; Schenetti, Luisa; F., Taddei. - In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS II. - ISSN 0300-9580. - STAMPA. - 14:(1973), pp. 1926-1929.

1H Nuclear Magnetic Resonance Spectra of the Imidazo[2,1-b]thiazole System

LAZZERETTI, Paolo;SCHENETTI, Luisa;
1973

Abstract

Some imidazo[2,1-b]thiazoles have been subjected to a 1H n.m.r. investigation. The aromatic character of this ring system, in connection with proton shielding, has been tested with coupled Hartree-Fock calculations of ring current effects, and it seems that the main differences in the chemical shifts relative to the single ring heterocycles are due to this kind of perturbation. A long-range coupling constant over six bonds has also been observed which implies a coupling mechanism involving the sulphur atom.
1973
14
1926
1929
1H Nuclear Magnetic Resonance Spectra of the Imidazo[2,1-b]thiazole System / L., Marchetti; L., Pentimalli; Lazzeretti, Paolo; Schenetti, Luisa; F., Taddei. - In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS II. - ISSN 0300-9580. - STAMPA. - 14:(1973), pp. 1926-1929.
L., Marchetti; L., Pentimalli; Lazzeretti, Paolo; Schenetti, Luisa; F., Taddei
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/454539
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