It is shown that the electric shielding tensor of a nucleus within a molecule is related to the polarisability of the corresponding atom. The condition for the electrostatic equilibrium, satisfied by the nuclear shieldings, is the Thomas-Reiche-Kuhn sum rule, and a gauge-invariance condition for the magnetisability. These achievements suggest that a unitary and synthetic theoretical framework for electric and magnetic second-order properties can be built up, where the nuclear electric shielding concept plays a major role.

Nuclear electric shielding and its connections with other second-order properties / Lazzeretti, Paolo; R., Zanasi. - In: JOURNAL OF MOLECULAR STRUCTURE. THEOCHEM. - ISSN 0166-1280. - STAMPA. - 120:(1985), pp. 265-275.

Nuclear electric shielding and its connections with other second-order properties

LAZZERETTI, Paolo;
1985-01-01

Abstract

It is shown that the electric shielding tensor of a nucleus within a molecule is related to the polarisability of the corresponding atom. The condition for the electrostatic equilibrium, satisfied by the nuclear shieldings, is the Thomas-Reiche-Kuhn sum rule, and a gauge-invariance condition for the magnetisability. These achievements suggest that a unitary and synthetic theoretical framework for electric and magnetic second-order properties can be built up, where the nuclear electric shielding concept plays a major role.
120
265
275
Nuclear electric shielding and its connections with other second-order properties / Lazzeretti, Paolo; R., Zanasi. - In: JOURNAL OF MOLECULAR STRUCTURE. THEOCHEM. - ISSN 0166-1280. - STAMPA. - 120:(1985), pp. 265-275.
Lazzeretti, Paolo; R., Zanasi
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/454505
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