Calculation shows that the proton–proton spin–spin coupling in methane is very sensitive to the interbond angle involving thecoupled protons, a result which leads to the prediction of primary isotope effects on 2J(H,H) in agreement with experimental results for geminal deuterium isotope effects in related compounds.

The Proton Spin-Spin Coupling Surface in Methane. A Test of the J(H,H) J(H,D) Rule for Geminal Protons / W. T., Raynes; Lazzeretti, Paolo; R., Zanasi; P. W., Fowler. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 1985:(1985), pp. 1538-1540.

The Proton Spin-Spin Coupling Surface in Methane. A Test of the J(H,H) J(H,D) Rule for Geminal Protons

LAZZERETTI, Paolo;
1985

Abstract

Calculation shows that the proton–proton spin–spin coupling in methane is very sensitive to the interbond angle involving thecoupled protons, a result which leads to the prediction of primary isotope effects on 2J(H,H) in agreement with experimental results for geminal deuterium isotope effects in related compounds.
1985
1538
1540
The Proton Spin-Spin Coupling Surface in Methane. A Test of the J(H,H) J(H,D) Rule for Geminal Protons / W. T., Raynes; Lazzeretti, Paolo; R., Zanasi; P. W., Fowler. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 1985:(1985), pp. 1538-1540.
W. T., Raynes; Lazzeretti, Paolo; R., Zanasi; P. W., Fowler
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/454501
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