It is shown via a series of numerical tests on the camphor molecule, C10H16O, that the naturally occurringd-enantiomer is energetically stabilized with respect to its mirror image by electroweak force. The calculatedenergy difference between enantiomers, about 1.5310219 hartree, is roughly eight orders of magnitude smallerthan the upper bound suggested by available spectroscopic investigations on the frequency of a spectroscopictransition. However, such a difference is about ten times larger than previous estimates of parity-violatingenergy contributions reported in the literature for other chiral molecules, which makes the idea of electroweakstabilization of one enantiomer more reliable than expected before.

Energetic Stabilization of d-Camphor via Weak Neutral Currents / Lazzeretti, Paolo; R., Zanasi; Faglioni, Francesco. - In: PHYSICAL REVIEW E. - ISSN 1063-651X. - STAMPA. - 60:(1999), pp. 871-874. [10.1103/PhysRevE.60.871]

Energetic Stabilization of d-Camphor via Weak Neutral Currents

LAZZERETTI, Paolo;FAGLIONI, Francesco
1999

Abstract

It is shown via a series of numerical tests on the camphor molecule, C10H16O, that the naturally occurringd-enantiomer is energetically stabilized with respect to its mirror image by electroweak force. The calculatedenergy difference between enantiomers, about 1.5310219 hartree, is roughly eight orders of magnitude smallerthan the upper bound suggested by available spectroscopic investigations on the frequency of a spectroscopictransition. However, such a difference is about ten times larger than previous estimates of parity-violatingenergy contributions reported in the literature for other chiral molecules, which makes the idea of electroweakstabilization of one enantiomer more reliable than expected before.
1999
60
871
874
Energetic Stabilization of d-Camphor via Weak Neutral Currents / Lazzeretti, Paolo; R., Zanasi; Faglioni, Francesco. - In: PHYSICAL REVIEW E. - ISSN 1063-651X. - STAMPA. - 60:(1999), pp. 871-874. [10.1103/PhysRevE.60.871]
Lazzeretti, Paolo; R., Zanasi; Faglioni, Francesco
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/454417
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