It is shown via a series of numerical tests on the camphor molecule, C10H16O, that the naturally occurringd-enantiomer is energetically stabilized with respect to its mirror image by electroweak force. The calculatedenergy difference between enantiomers, about 1.5310219 hartree, is roughly eight orders of magnitude smallerthan the upper bound suggested by available spectroscopic investigations on the frequency of a spectroscopictransition. However, such a difference is about ten times larger than previous estimates of parity-violatingenergy contributions reported in the literature for other chiral molecules, which makes the idea of electroweakstabilization of one enantiomer more reliable than expected before.
Energetic Stabilization of d-Camphor via Weak Neutral Currents / Lazzeretti, Paolo; R., Zanasi; Faglioni, Francesco. - In: PHYSICAL REVIEW E. - ISSN 1063-651X. - STAMPA. - 60:(1999), pp. 871-874. [10.1103/PhysRevE.60.871]
Energetic Stabilization of d-Camphor via Weak Neutral Currents
LAZZERETTI, Paolo;FAGLIONI, Francesco
1999
Abstract
It is shown via a series of numerical tests on the camphor molecule, C10H16O, that the naturally occurringd-enantiomer is energetically stabilized with respect to its mirror image by electroweak force. The calculatedenergy difference between enantiomers, about 1.5310219 hartree, is roughly eight orders of magnitude smallerthan the upper bound suggested by available spectroscopic investigations on the frequency of a spectroscopictransition. However, such a difference is about ten times larger than previous estimates of parity-violatingenergy contributions reported in the literature for other chiral molecules, which makes the idea of electroweakstabilization of one enantiomer more reliable than expected before.Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris