Me3SiCl-DMSO combine to form a reagent which transforms alkenes (e.g., BuCMe:CH2, 1-methylcyclohepxene, norbornene) into 2-chloroalkyl Me sulfides [e.g., BuCMeClCH2SMe, 1-chloro-1-methyl-2-(methylthio)cyclohexane, chloro(methylthio)norbornane I] regio- and stereoselectively.
THE REACTION OF THRICHLORO AND TRIMETHYLBROMOSILANE-DIMETHYLSULFOXIDE REAGENT SYSTEM ON ALKENES / Bellesia, Franco; Ghelfi, Franco; Pagnoni, Ugo Maria; Pinetti, Adriano. - In: JOURNAL OF CHEMICAL RESEARCH. SYNOPSES. - ISSN 0308-2342. - STAMPA. - /:(1987), pp. 238-239.
THE REACTION OF THRICHLORO AND TRIMETHYLBROMOSILANE-DIMETHYLSULFOXIDE REAGENT SYSTEM ON ALKENES
BELLESIA, Franco;GHELFI, Franco;PAGNONI, Ugo Maria;PINETTI, Adriano
1987
Abstract
Me3SiCl-DMSO combine to form a reagent which transforms alkenes (e.g., BuCMe:CH2, 1-methylcyclohepxene, norbornene) into 2-chloroalkyl Me sulfides [e.g., BuCMeClCH2SMe, 1-chloro-1-methyl-2-(methylthio)cyclohexane, chloro(methylthio)norbornane I] regio- and stereoselectively.
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