Clusters can be expanded and their magnetic properties tuned by the addn. of suitable metal-complex ligands. By using this method, [Cu6{(PhSiO2)6}2{(NC)Cu(tmpa)}4](PF6)4 was rationally designed by self-assembly of four {(NC)Cu(tmpa)}+ units around a robust hexacopper(II)-siloxanolate cage (tmpa = tris(2-pyridylmethyl)amine).
Towards Stepwise Cluster Assembly: a Decacopper(II) Complex Obtained by Controlled Expansion of a Metallasiloxane Cage / G. L., Abbati; A., Caneschi; Cornia, Andrea; FABRETTI COSTANTINO, Antonio; Y. A., Pozdniakova; O. I., Shchegolikhina. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 41:(2002), pp. 4517-4520. [10.1002/1521-3773(20021202)41:23<4517::AID-ANIE4517>3.0.CO;2-G]
Towards Stepwise Cluster Assembly: a Decacopper(II) Complex Obtained by Controlled Expansion of a Metallasiloxane Cage
CORNIA, Andrea;FABRETTI COSTANTINO, Antonio;
2002
Abstract
Clusters can be expanded and their magnetic properties tuned by the addn. of suitable metal-complex ligands. By using this method, [Cu6{(PhSiO2)6}2{(NC)Cu(tmpa)}4](PF6)4 was rationally designed by self-assembly of four {(NC)Cu(tmpa)}+ units around a robust hexacopper(II)-siloxanolate cage (tmpa = tris(2-pyridylmethyl)amine).
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