Palladium(II) complexes with two thiophene derivatives bearing alkylsulfanyl chains, i.e., 3-(n-butylsulfanyl)thiophene and 4,4´-bis(n-butylsulfanyl)-2,2´-bithiophene, are synthesised and spectroscopically and electrochemically characterised. The molecular structure of PdCl2[3-(n-butylsulfanyl)thiophene]2 was determined by X-ray analysis. The properties of the complexes have been compared with those of PdCl2[3,3´-bis(n-butylsulfanyl)-2,2´-bithiophene] and of a conductive polymer partially coordinated with Pd(II), previously synthesised by us. We found that Pd(11) ions can coordinate sulfanyl sulfur atoms both in cis and trans configuration, leading to a reticulate material, where some kind of interchain bridging may be reasonably supposed to enhance the bulk conductivity.
Palladium(II) derivatives of alkylsulfanyl substituted thiophenes as precursors of inorganic polymers: Spectroscopic, electrochemical investigations and X-ray crystal structure of trans-PdCl2[3-(butylsulfanyl)thiophene](2) / Antolini, Luciano; G., Minghetti; Mucci, Adele; Parenti, Francesca; Pigani, Laura; G., Sanna; Seeber, Renato; Zanardi, Chiara. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 358:11(2005), pp. 3033-3040.
Data di pubblicazione: | 2005 |
Titolo: | Palladium(II) derivatives of alkylsulfanyl substituted thiophenes as precursors of inorganic polymers: Spectroscopic, electrochemical investigations and X-ray crystal structure of trans-PdCl2[3-(butylsulfanyl)thiophene](2) |
Autore/i: | Antolini, Luciano; G., Minghetti; Mucci, Adele; Parenti, Francesca; Pigani, Laura; G., Sanna; Seeber, Renato; Zanardi, Chiara |
Autore/i UNIMORE: | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.ica.2005.03.043 |
Rivista: | |
Volume: | 358 |
Fascicolo: | 11 |
Pagina iniziale: | 3033 |
Pagina finale: | 3040 |
Codice identificativo ISI: | WOS:000230179300008 |
Codice identificativo Scopus: | 2-s2.0-20144371600 |
Citazione: | Palladium(II) derivatives of alkylsulfanyl substituted thiophenes as precursors of inorganic polymers: Spectroscopic, electrochemical investigations and X-ray crystal structure of trans-PdCl2[3-(butylsulfanyl)thiophene](2) / Antolini, Luciano; G., Minghetti; Mucci, Adele; Parenti, Francesca; Pigani, Laura; G., Sanna; Seeber, Renato; Zanardi, Chiara. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 358:11(2005), pp. 3033-3040. |
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