A new application of (PhO)(3)P-halogen-based reagents to the synthesis of vinyl halides and gem-dihalides is described. Vinyl halides were prepared in good to excellent yields from enolizable ketones, whereas aldehydes afforded the corresponding gem-dihalides. The halogenation proceeded smoothly under mild conditions.
A Mild Synthesis of Vinyl Halides and gem-Dihalides Using Triphenyl Phosphite–Halogen-based Reagents / SPAGGIARI, Alberto; VACCARI, Daniele; DAVOLI, Paolo; TORRE, Giovanni; PRATI, Fabio. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 72:6(2007), pp. 2216-2219. [10.1021/jo061346g]
A Mild Synthesis of Vinyl Halides and gem-Dihalides Using Triphenyl Phosphite–Halogen-based Reagents
SPAGGIARI, Alberto;VACCARI, Daniele;DAVOLI, Paolo;TORRE, Giovanni;PRATI, Fabio
2007
Abstract
A new application of (PhO)(3)P-halogen-based reagents to the synthesis of vinyl halides and gem-dihalides is described. Vinyl halides were prepared in good to excellent yields from enolizable ketones, whereas aldehydes afforded the corresponding gem-dihalides. The halogenation proceeded smoothly under mild conditions.
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