The structural and spectroscopic properties of [Cu(bipy)(tsasnO)2].2H2O are investigated. The complex crystallizes in the space group P2(1)/n, with a = 12.502(2), b = 15.298(2), c = 18.901(8) angstrom, beta = 96.80(2)-degrees and Z = 4. The complex consists of discrete [Cu(bipy)(tsasnO)2] units and lattice water molecules. The Cu(II) ion is coordinated to two bipy nitrogens and two carboxylate oxygens from two aminoacidate anions in a square-planar geometry.
Solid state behaviour of N-tosyl-DL-asparagine-Cu(II)-2,2'-bipyridine system / Forti, Luca; Saladini, Monica; Sola, Marco. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 187:(1991), pp. 197-200. [10.1016/S0020-1693(00)90394-3]
Solid state behaviour of N-tosyl-DL-asparagine-Cu(II)-2,2'-bipyridine system
FORTI, Luca;SALADINI, Monica;SOLA, Marco
1991
Abstract
The structural and spectroscopic properties of [Cu(bipy)(tsasnO)2].2H2O are investigated. The complex crystallizes in the space group P2(1)/n, with a = 12.502(2), b = 15.298(2), c = 18.901(8) angstrom, beta = 96.80(2)-degrees and Z = 4. The complex consists of discrete [Cu(bipy)(tsasnO)2] units and lattice water molecules. The Cu(II) ion is coordinated to two bipy nitrogens and two carboxylate oxygens from two aminoacidate anions in a square-planar geometry.
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