The synthetic approach to methyl N-(tert-butoxycarbonyl) -S- (3-thienyl)-L-cysteinate (1) and methyl N-(tert-butoxycarbonyl)-S-[2-(3-thienyl)ethyl]-L-eysteinate (2) through tosylate intermediates is reported and discussed. These compounds, which combine the properties of the cysteine side-chain with those of the thiophene ring represent both potential bioactive molecules and interesting synthons for the development of new materials.
Synthesis of two novel cysteine-functionalized thiophenes / Cagnoli, Rita; M., Lanzi; Mucci, Adele; Parenti, Francesca; Schenetti, Luisa. - In: SYNTHESIS. - ISSN 0039-7881. - STAMPA. - 2:(2005), pp. 267-271. [10.1055/s-2004-834930]
Synthesis of two novel cysteine-functionalized thiophenes
CAGNOLI, Rita;MUCCI, Adele;PARENTI, Francesca;SCHENETTI, Luisa
2005
Abstract
The synthetic approach to methyl N-(tert-butoxycarbonyl) -S- (3-thienyl)-L-cysteinate (1) and methyl N-(tert-butoxycarbonyl)-S-[2-(3-thienyl)ethyl]-L-eysteinate (2) through tosylate intermediates is reported and discussed. These compounds, which combine the properties of the cysteine side-chain with those of the thiophene ring represent both potential bioactive molecules and interesting synthons for the development of new materials.
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