The acid dissociation constants of 2,4,6-trinitrophenol (picric acid) were determined in N,N-dimethylformamide and ethane-1,2-diol from -10 to +80-degrees-C and in two N,N-dimethylformamide + ethane-1,2-diol mixtures from +20 to +80-degrees-C using the conductometric method. The experimental conductivity data were analyzed by means of the Fuoss-Hsla equation, and the dissociation constants were fitted by the integrated Van't Hoff equation.
Dissociation constants of picric acid in mixtures of N,N-dimethylformamide + ethane-1,2-diol / F., Corradini; Marchetti, Andrea; M., Tagliazucchi; Tassi, Lorenzo; Tosi, Giuseppe. - In: JOURNAL OF CHEMICAL AND ENGINEERING DATA. - ISSN 0021-9568. - ELETTRONICO. - 37:(1992), pp. 191-194.
Dissociation constants of picric acid in mixtures of N,N-dimethylformamide + ethane-1,2-diol
MARCHETTI, Andrea;TASSI, Lorenzo;TOSI, Giuseppe
1992-01-01
Abstract
The acid dissociation constants of 2,4,6-trinitrophenol (picric acid) were determined in N,N-dimethylformamide and ethane-1,2-diol from -10 to +80-degrees-C and in two N,N-dimethylformamide + ethane-1,2-diol mixtures from +20 to +80-degrees-C using the conductometric method. The experimental conductivity data were analyzed by means of the Fuoss-Hsla equation, and the dissociation constants were fitted by the integrated Van't Hoff equation.
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